課程資訊
課程名稱
聚烯烴科技
Polyolefin Science and Technology 
開課學期
108-1 
授課對象
工學院  化學工程學系  
授課教師
鄒海雄 
課號
ChemE5067 
課程識別碼
524 U2260 
班次
 
學分
3.0 
全/半年
半年 
必/選修
選修 
上課時間
星期四7,8,9(14:20~17:20) 
上課地點
綜503 
備註
化工選修課程。
總人數上限:50人 
Ceiba 課程網頁
http://ceiba.ntu.edu.tw/1081ChemE5067_ 
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課程概述

Science and technology of polyolefins, most specifically polyolefins based on C2 to C5 olefins obtained from steam cracking. The course will cover olefin polymerization methods (radical, ionic, and metal-coordinated insertion) and kinetics (activation, initiation, propagation, termination, transfer, and mathematic approaches), homogeneous and heterogeneous catalyst technology (activator, initiator, support, electron donor, Ziegler-Natta, metallocene, and organometallic), polymerization reactor dynamics (CSTR and tubular, slurry, solution, gas-phase, and hybrid, reactor granule technology, heat and mass transfer), structural characterization (molecular weights, composition, rheology, and morphology), structure and property relationships (plastics, rubbers, tackifiers, crystallization, crosslinking, self-association, mechanisms and mechanics of plasticity, elasticity, and adhesion), and polyolefin blends and compounds (thermodynamics and dynamics of blends and compounds). 

課程目標
Polyolefins account for majority of plastics, synthetic thermoset rubbers, thermoplastic elastomers and tackifiers produced and are the backbone of polymer industries, both in Taiwan and globally. This course will prepare the students to work in the polymer industry or to continue to pursue research in polymers. This course will also teach the students to apply chemical engineering fundamentals, thermodynamics, kinetics, mechanics, engineering mathematics, catalysis science, reactor dynamics, materials and polymer science, to the science and technology of design, synthesis, and manufacturing of polyolefins. 
課程要求
Thermodynamics, Kinetics, Engineering Mathematics, Mass and Energy Balance, Organic Chemistry, Analytic Chemistry, Physical Chemistry (Chemical Engineering Required Classes from Freshman to Junior) 
預期每週課後學習時數
 
Office Hours
 
指定閱讀
Lecture notes as a text book "Polyolefin science and technology", 8 chapters-introduction, polymerization, catalysis, reactor, characterization, plastics, rubbers, and blends. 
參考書目
L. H. Sperling, “Introduction to Physical Polymer Science”, 4th ed., 2006
J. B. P. Soares and T. F. L. McKenna, “Polyolefin Reaction Engineering”, 2012
M. Rubinstein and R. H. Colby, “Polymer Physics”, 2003
P. C. Hiemenz and T. P. Lodge, “Polymer Chemistry”, 2nd ed., 2007
W. W. Graessley, “Polymeric Liquids and Networks: Structure and Properties”, 2004
E. Piorkowska and G. C. Rutledge, “Handbook of Polymer Crystallization”, 2013
J. Scheirs and W. Kaminsky, “Metallocene-Based Polyolefins”, Vol. 1, 2000 
評量方式
(僅供參考)
 
No.
項目
百分比
說明
1. 
Homework 
20% 
 
2. 
Midterm 
35% 
 
3. 
Final 
45% 
 
 
課程進度
週次
日期
單元主題
第1週
9/12  Introduction to polyolefins 
第2週
9/19  Olefin polymerization kinetics 
第3週
9/26  Polyolefin microstructural analysis 
第4週
10/03  Olefin polymerization catalysts 
第5週
10/10  Holiday 
第6週
10/17  Organometallic coordination insertion catalysts 
第7週
10/24  Polyolefin reaction engineering 
第8週
10/31  Heterogeneous catalysis polyolefin reactor dynamics 
第9週
11/07  Mid term examination 
第10週
11/14  Molecular weight and composition characterization 
第11週
11/21  Rhoelogy and morphology of polyolefins 
第12週
11/28  Polyolefin crystallization 
第13週
12/05  Structure and property of polyolefin plastics/plastomers 
第14週
12/12  Polyolefin rubber elasticity 
第15週
12/19  Structure/property of polyolefin rubber/elastomer/tackifier 
第16週
12/26  Thermodynamics of polymer blends 
第17週
1/02  Polyolefin blends and compounds 
第18週
1/09  Final examination